Police and protesters in the Ukrainian capital Kiev were locked in a tense standoff early on Thursday, as the US threatened to impose sanctions over street battles which have claimed three lives.
Opposition leaders called for "calm" and an eight-hour truce ahead of fresh talks with President Viktor Yanukovych, which witnesses said appeared to be holding.
Police and protesters clashed again overnight, turning an area at the heart of the city into a virtual war zone with demonstrators setting fire to barricades, hurling stones and Molotov cocktails and police using tear gas, stun grenades and rubber bullets.
Sky's Katie Stallard, in Kiev, said: "Protesters also burned tyres, mattresses, whatever they could find to keep going, and reinforcing barricades too.
Fires continue to rage in central Kiev"They have made homemade shields out of planks of wood and are rehearsing their tactical formations - how they plan to stand together and how they plan to protect themselves."
Earlier, opposition leaders had told them to go on the offensive on Thursday. They said Wednesday's peace talks had proved useless.
Vitali Klitschko said if this involved going onto the streets under bullets - that is what he and they were prepared to do.
They have on Mr Yanukovych to announce early elections within 24 hours or face more violence on the streets.
And have demanded he dismiss the government and scrap harsh anti-protest legislation.
Demonstrators have made their own shields out of wood to defend themselvesThe leader of the opposition Fatherland party Arseniy Yatsenyuk said he was ready to die for the cause.
"If he does not go down that path then we will go forwards together and if it means a bullet to the head, then it is a bullet to the head. Viktor Yanukovych you have 24 hours. Take a decision. I have taken my decision," he said to cheers, speaking to around 40,000 people in Kiev's Independence Square.
Mr Klitschko added: "Early elections will change the situation without bloodshed and we will do everything to achieve that."
Medical staff in Kiev told Sky News that three people have been killed during the clashes.
Two protesters died after being shot, while another died from injuries sustained in a fall. One of the dead protesters was named locally as Serhiy Nihoyna.
Prime Minister Mykola Azarov said the police did not have live ammunition and that opposition leaders should be held responsible for the deaths.
Opposition leaders have told protesters to go on the offensive on ThursdayPolice have thrown stun grenades and broken through protesters' barricades, made from burnt-out buses.
Protesters have also lobbed petrol bombs at police during ferocious clashes in the city's snow-covered streets.
During confrontations on Wednesday, riot police beat and shot at protesters, volunteer medics and journalists. The Interior Ministry said 70 protesters have been arrested.
The US State Department has threatened to impose sanctions against the Ukraine in response to the continued use of violence against protesters.
Spokeswoman Marie Harf said the US would continue to call upon Mr Yanukovych "to protect the democratic rights of all Ukrainians, including the rights of peaceful protest".
Image said to show one of the dead, Serhiy Nihoyna (Pic: Serhiy Proskurnia)"I don't have more details on what those sanctions might look like, but we will continue to consider additional steps, as I said, including sanctions, in response to the use of violence," she said.
The rioting intensified when some 200,000 took to the streets at the weekend in a show of anger over the new anti-protest laws rushed through by Mr Yanukovych.
The laws allow for jail terms of up to five years for those who blockade public buildings. They also ban protesters from wearing masks or helmets.
Meanwhile, Russia said it would not intervene, according to President Vladimir Putin's spokesman Dmitry Peskov.
"We consider we do not have the right to intervene in any way in the internal affairs of our brother Ukraine. That's unacceptable and Russia has not done this and will not do it," he said in an interview published on the website of Komsomolskaya Pravda.
:: Watch Sky News live on television, on Sky channel 501, Virgin Media channel 602, Freeview channel 82 and Freesat channel 202.
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